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Toward understanding the morphology-related crack initiation and propagation behavior in polypropylene systems as assessed by the essential work of fracture approach

 

作者: J. Karger-kocsis,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1999)
卷期: Volume 38, issue 5-6  

页码: 635-646

 

ISSN:0022-2348

 

年代: 1999

 

DOI:10.1080/00222349908248127

 

出版商: Taylor & Francis Group

 

关键词: Elastomeric PP;Essential work of fracture;Ethylene-co-butylene copolymers;Plastic zone;Polypropylene blends;Process zone;Rubber-toughened polypropylene;Toughness.

 

数据来源: Taylor

 

摘要:

Fracture mechanical terms related to the crack initiation and propagation, respectively, were assessed by the essential work of fracture (EWF) method for compression-molded polypropylene (PP) blends and elastomeric polypropylenes (ELPPs). The resistance to crack initiation (RCI) was characterized by the essential work of fractureweTheweof the PP blends with 20 vol% ethyiene-co-butylene (EB) copolymers of various butylene (B) contents (58 and 90 wt%) and morphology (EB58 is amorphous, whereas EB90 is semicrystalline) increased with increasing butylene content and thus crystallinity. At the same time, in the slope of the EWF resistance curves, which inform about the resistance to crack propagation (RCP) of the PP/EB blends, an adverse change was observed. For the ELPPs of various crystallinity and morphology, the opposite tendency was found, that is, the RCI decreased, but the RCP increased with increasing crystallinity. The above findings were interpreted by considering the morphology and its rearrangement due to loading. It was suggested that the RCI is improved by the order of the crystalline structure and by the density of tie molecules that transfer the stress from the amorphous toward the crystalline phase. On the other hand, the RCP is controlled by a stress redistribution process that is influenced by possible changes in the local morphology.

 

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