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Theory of ferroelectric‐paraelectric transitions in VF2/F4E random copolymers

 

作者: Renshi Zhang,   P. L. Taylor,  

 

期刊: Journal of Applied Physics  (AIP Available online 1993)
卷期: Volume 73, issue 3  

页码: 1395-1402

 

ISSN:0021-8979

 

年代: 1993

 

DOI:10.1063/1.353260

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The problem of calculating the free energy of a ferroelectric random copolymer is discussed in terms of a mean field model. The intrachain interactions are treated in detail, but the interchain interactions are approximated as a function only of the torsional angle at a chain segment and of an order parameter determined by averaging over the conformations of all chains. This formalism is applied to a simple model of the random copolymer of vinylidene fluoride and tetrafluoroethylene. The results of this calculation are combined with the known Curie temperatures of these copolymers to determine the magnitude of the effective interchain interaction over a range of copolymer compositions.

 

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