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Gel permeation chromatography: Automatic data acquisition and reduction in real‐time with a process computer

 

作者: G. R. Meira,   A. F. Johnson,  

 

期刊: Polymer Engineering&Science  (WILEY Available online 1981)
卷期: Volume 21, issue 1  

页码: 57-63

 

ISSN:0032-3888

 

年代: 1981

 

DOI:10.1002/pen.760210110

 

出版商: Society of Plastics Engineers, Inc.

 

数据来源: WILEY

 

摘要:

AbstractA real‐time computer system is described which minimizes the total analysis time in gel permeation chromatography by automatically acquiring the data, performing the necessary calculations and displaying the molecular weight distribution and molecular weight averages as soon as the polymer peak has eluted. The calculation method described here is valid for linear homopolymers only, and does not include corrections for instrumental peak broadening. The experimental results show good reproducibility and precision. On‐line changes of the constants and other parameters may be implemented by means of an auxiliary program which runs in parallel with the data analysis program. A system such as that described here is suitable for utilization as a measurement technique in process control applications. The programs are written in CORAL 66 for a Ferranti Argus 700 E compu

 

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