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Isopiestic determination of the osmotic and activity coefficients of aqueous Lu2(SO4)3at 25°C

 

作者: JosephA.Rard,  

 

期刊: Journal of Solution Chemistry  (Springer Available online 2004)
卷期: Volume 19, issue 6  

页码: 525-541

 

ISSN:0095-9782

 

年代: 2004

 

DOI:10.1007/BF00647027

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

Osmotic coefficients have been measured for aqueous Lu2(SO4)3solutions from 0.12402 to 0.89631 mol-kg−1at 25°C by use of the isopiestic method; these measurements extend into the supersaturated molality region. Since there was a lack of activity data for Lu2(SO4)3solutions at lower molalities, they were approximated by equating them to results for La2(SO4)3from freezing temperature depression measurements. The combined osmotic coefficients were then used to derive mean molal activity coefficients for Lu2(SO4)3solutions. The osmotic coefficients decrease to 0.307 as their minimum value and the mean molal activity coefficients decrease to 0.0069. When these activities were combined with our previously reported solubility of 0.6260±0.0017 mol-kg−1for Lu2(SO4)3·8H2O, a thermodynamic solubility product of 2.3×10−10was obtained. This value yields the Gibbs energy of formation ΔGf°(Lu2(SO4)3·8H2O, cr)=−5518.9

 

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