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A model of adaptive links in nonlinear viscoelasticity

 

作者: Aleksey D. Drozdov,  

 

期刊: Journal of Rheology  (AIP Available online 1997)
卷期: Volume 41, issue 6  

页码: 1223-1245

 

ISSN:0148-6055

 

年代: 1997

 

DOI:10.1122/1.550849

 

出版商: The Society of Rheology

 

关键词: Adaptive links;Solid, viscoelastic;Constitutive equations;Separability

 

数据来源: AIP

 

摘要:

A new constitutive model is derived for the nonlinear viscoelastic behavior of polymers which do not possess the separability property. The model is based on the concept of adaptive links (a version of the theory of transient networks). It is assumed that the response of a link is essentially nonlinear, and the rates of breakage and reformation depend on the strain intensity. With reference to the Eyring concept of thermally activated processes, a new equation is proposed to describe the effect of strains on reformation of adaptive links. Adjustable parameters of the model are found by using experimental data for polycarbonate and an epoxy glass in the standard relaxation tests. Comparison of experimental data in dynamic tests with results of numerical simulation shows that the model correctly predicts the nonlinear viscoelastic response.

 

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