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Light scattering measurements of anisotropic viscoelastic coefficients of a main-chain polymer nematic liquid crystal

 

作者: Sin-Doo Lee,   R.B. Meyer,  

 

期刊: Liquid Crystals  (Taylor Available online 1990)
卷期: Volume 7, issue 1  

页码: 15-29

 

ISSN:0267-8292

 

年代: 1990

 

DOI:10.1080/02678299008029190

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

We report the first systematic measurements of elastic coefficients and viscosities that clearly demonstrate the distinction between rigid and semiflexible behaviour of a main-chain polymer nematic liquid crystal, a solution of poly-γ-benzyl glutamate (PBG) in mixed organic solvents. Quasi-elastic Rayleigh scattering studies show a crossover which occurs at a molecular chain length near the persistence length of PBG as the chain length increases. The results are in qualitatively good agreement with recent theoretical predictions for semiflexible chains. It is seen that bending distortions of an individual polymer play an important role in the fundamental nature of nematic elasticity and viscosity.

 

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