Chemical Kinetic Data Sheets for High‐Temperature Chemical Reactions
作者:
N. Cohen,
K. R. Westberg,
期刊:
Journal of Physical & Chemical Reference Data
(AIP Available online 1983)
卷期:
Volume 12,
issue 3
页码: 531-590
ISSN:0047-2689
年代: 1983
DOI:10.1063/1.555692
出版商: AIP
数据来源: AIP
摘要:
A new program for the compilation and evaluation of chemical kinetic data is described. Rate coefficient measurements are assessed for probable accuracy and precision. Transition‐state theory is often used to extrapolate measurements to higher temperatures. For every reaction reviewed, a recommended rate coefficient is given in the formk=ATn×exp(−B/T). Pertinent data and conclusions are summarized on a two‐page Data Sheet, each sheet covering one reaction or occasionally two or three closely related reactions. Twenty‐seven Data Sheets are presented for reactions important in modeling and understanding chemical lasers, hydrogen–oxygen combustion, hydrocarbon oxidation, and aluminum or boron propellant systems.
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