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Isotope Studies of Hydrogen and Oxygen in Ground Ice - Experiences with the Equilibration Technique

 

作者: H. Meyer,   L. Schönicke,   U. Wand,   H.W. Hubberten,   H. Friedrichsen,  

 

期刊: Isotopes in Environmental and Health Studies  (Taylor Available online 2000)
卷期: Volume 36, issue 2  

页码: 133-149

 

ISSN:1025-6016

 

年代: 2000

 

DOI:10.1080/10256010008032939

 

出版商: Taylor & Francis Group

 

关键词: Calibration;Equilibration technique;Ground ice;Hydrogen-2;Ice wedges;Oxygen-18;Natural abundance;Paleoclimate;Siberia;Small sample size;Stable isotopes

 

数据来源: Taylor

 

摘要:

Equilibration technique suitable for a large amount ofsamples is described for hydrogen and oxygen isotope analyses of ground ice, especially ice wedges, including the sampling strategy and the analytical procedure as well as the calibration of the Finnigan MAT Delta-Smass spectrometer in June, 1999. Since for future analyses of ice wedges, a higher sampling resolution with limited sample volume is required, the limit of the equliibration technique for small water samples size of between 0.05 and 5 ml was checked. For water samples smaller than 1ml, corresponding to a molar ratio [H2O]/[H2] of smaller than 0.994, a balance correction has to be applied. The experimental errors due to partial evaporation during evacuation, the balance calcultion of the isotope equilibration process, the linearity as well as memory effects of the mass spectrometer for smaples with large differences in δ18O and δD are tackled in this paper. In the polar regions of Northern Siberia without Late Pleistocene and Holocene glaciation, ground ice is used as an archive for paleoclimate studies. First results of stable isotope measurements on ice wedges clearly show a shift towards heavier isotopes and thus warmer winter temperatures as well as a change in the source of the precipitation between Late Pleistocene and Holocene. These results indicate the high potential of ground ice for paleoclimate studies.

 

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