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Lodestone‐explanation for magnetic properties and characterization of the source of magnetic hardening

 

作者: P. J. Wasilewski,  

 

期刊: Journal of Applied Physics  (AIP Available online 1979)
卷期: Volume 50, issue B3  

页码: 2428-2430

 

ISSN:0021-8979

 

年代: 1979

 

DOI:10.1063/1.326975

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A Class I lodestone is a massive iron ore which owes its magnetic hardness to oxidation. Oxidation of the Fe3O4results in a fine intergrowth of &ggr; Fe2O3in host Fe3O4, a requisite for all lodestones studied. The natural remanence (NRM) to saturation isothermal remanence (ISR) values are ≳0.5 compared to values <0.05 for most other naturally magnetized materials. The behavior of the lodestone magnetization has been studied from 4 K to 825 K, and x‐ray, optical and transmission electron microscopy data have been used to confirm the &ggr;‐FeO3‐Fe3O4epitaxy. On heating to 250 °C coercive force (HC), remanent coercive force (HR), and ISRdecrease, while about 70&percent; of the NRM is lost. On returning to ambient temperature an increase in saturation magnetization (IS) is noted which can be interpreted as an ordering of the &ggr; Fe2O3. Further heating to 425 °C results in destruction of the &ggr; Fe2O3, a complete destruction of the lodestone remanence, while Hc, HR, and ISRincrease. Beyond 425 °C the material behaves normally. On returning to ambient temperatre Hcand HRrecover in smooth and continuous fashion while the thermoremanence (TRM) acquired in the geomagnetic field is less than 5&percent; of the NRM value. Initial and final HCand HRvalues are the same. However as the thickness of the &ggr; Fe2O3lamellae increase the final HCand HRvalues are reduced. ISis reduced by an amount dependent on the &ggr; Fe2O3?&agr;Fe2O3conversion. The intense lodestone remanence was apparently acquired during the oxidation of Fe3O4, though the lodestone could be charged by fields associated with a lightening discharge.

 

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