Influence of expansion of polymer molecules in solution on non‐newtonian flow behavior
作者:
Yoshio Ito,
Shoji Shiina,
Ikuo Tokue,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1982)
卷期:
Volume 183,
issue 2
页码: 505-510
ISSN:0025-116X
年代: 1982
DOI:10.1002/macp.1982.021830219
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractNon‐Newtonian viscosity could be explained by the Graessely entanglement viscosity theory modified by a frictional viscosity for moderately concentrated solutions of polydimethyIsiloxanes over a range of shear rates from lower to upper‐Newtonian flow. The expansion of a polymer molecule was kept under control by use of solvents with different dissolving powers of the polymer. The result shows that only the frictional viscosity is strongly related to the degree of expansion of a polymer molecule in solution and that Graessley's plots are independent of that. Extrapolation of the frictional viscosity versus concentration curves to 100wt.‐% show a common value of 0,09 Pa·s in spite of different degrees of expansion of the polymer molecules in solution. This common value was equal to the viscosity value for melt polymer with the same molecular weight as a polymer segment. It is concluded that the frictional viscosity is caused by solvent‐solvent, solvent‐polymer segment, and segment‐segment
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