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Mechanochemical Transformations of Ag, Hg AND Pb Cyanometallates in KBr Pressed Disks

 

作者: E. Reguera,   J. Fernàndez-Bertràn,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1997）
卷期: Volume 30, issue 1  

页码: 89-98

 

ISSN:0038-7010

 

年代: 1997

 

DOI:10.1080/00387019708002592

 

出版商: Taylor & Francis Group

 

关键词: IR spectra;cyano complexes;mechanochemistry;ion exchange reactions

 

数据来源: Taylor

 

摘要:

The mechanochemical transformations of Ag, Hg and Pb cyano complexes (ferro-and ferricyanides, cobalticyanides, nitroprussides, hexacyanoplatinates and tetracyanonickellates) during milling and pressing with KBr have been studied using IR, XRD and Mossbauer techniques as sensors. Exchange of K+and the heavy metal cations is observed in all cases.

 

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