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First order transitions by conduction calorimetry: Application to deuterated potassium dihydrogen phosphate ferroelastic crystal under uniaxial pressure

 

作者: M. C. Gallardo,   J. Jime´nez,   M. Koralewski,   J. del Cerro,  

 

期刊: Journal of Applied Physics  (AIP Available online 1997)
卷期: Volume 81, issue 6  

页码: 2584-2589

 

ISSN:0021-8979

 

年代: 1997

 

DOI:10.1063/1.363922

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The specific heatcand the heat powerWexchanged by a Deuterated Potassium Dihydrogen Phosphate ferroelectric-ferroelastic crystal have been measured simultaneously for both decreasing and increasing temperature at a low constant rate (0.06 K/h) between 175 and 240 K. The measurements were carried out under controlled uniaxial stresses of 0.3 and 4.5±0.1 bar applied to face (110). AtTt=207.9K, a first order transition is produced with anomalous specific heat behavior in the interval where the transition heat appears. This anomalous behavior is explained in terms of the temperature variation of the heat power during the transition. During cooling, the transition occurs with coexistence of phases, while during heating it seems that metastable states are reached. Excluding data affected by the transition heat, the specific heat behavior agrees with the predictions of a 2-4-6 Landau potential in the range of 4–15 K belowTtwhile logarithmic behavior is obtained in the range fromTtto 1 K belowTt.Data obtained under 0.3 and 4.5 bar uniaxial stresses exhibit the same behavior. ©1997 American Institute of Physics.

 

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