Analysis of highly excited vibrational eigenstates
作者:
MichaelJ. Davis,
期刊:
International Reviews in Physical Chemistry
(Taylor Available online 1995)
卷期:
Volume 14,
issue 1
页码: 15-66
ISSN:0144-235X
年代: 1995
DOI:10.1080/01442359509353303
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Methods for the analysis of highly excited vibrational eigenstates are presented. These include semiclassical and hierarchical analyses, along with a discussion of the nature of eigenstates along a correlation diagram. The purpose of the analyses is to extract information from what often appear to be complicated, ‘unassignable’ eigenstates. In particular, I address how to rationalize the nature of eigenstates via the semiclassical analysis and how to extract information concerning assignability and energy flow from the hierarchical analysis. The study of the eigenstates along a correlation diagram, together with the semiclassical analysis, is undertaken to address the issue of the classical-quantum correspondence when the classical mechanics is chaotic.
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