Uphill Transport Driven by Hydrolysis of a Complex Partitioned into a Liquid Membrane: Application to the Preconcentration of Arsenic
作者:
JamesA. Cox,
Atul Bhatnagar,
期刊:
Analytical Letters
(Taylor Available online 1988)
卷期:
Volume 21,
issue 12
页码: 2307-2321
ISSN:0003-2719
年代: 1988
DOI:10.1080/00032718808059911
出版商: Taylor & Francis Group
关键词: mass transport;supported liquid membrane;graphite furnace;aluminum interference;phosphate interference
数据来源: Taylor
摘要:
AsI3is demonstrated to partition from a 9 M HC1, 0.10 M KI, 0.10 H ascorbic acid solution into kerosene and dodecane membranes which do not contain complexing agents. Subsequent hydrolysis at the membrane receiver interface causes a transport of As against its concentration gradient. A 60 minute experiment with a 4 mL receiver solution and a 200 mL sample permits the preconcentration of As by a factor of 16 ± 0.5. The interferences of aluminum and phosphate on the graphite furnace atomic absorption spectro-metric determination of As are eliminated. This transport mechanism, which has not been previously reported, may allow the range of species which can be preconcentrated by transport across supported liquid membranes to be significantly extended.
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