Luminescent Properties of the Hexakis(Nitrito)Europate(Iii) Ion [Eu(No2)6]3−
作者:
J.-C.G. Bunzli,
S. Petoud,
E. Moret,
期刊:
Spectroscopy Letters
(Taylor Available online 1999)
卷期:
Volume 32,
issue 1
页码: 155-163
ISSN:0038-7010
年代: 1999
DOI:10.1080/00387019909349974
出版商: Taylor & Francis Group
关键词: europium;luminescence;site symmetry;lifetime;nitrite
数据来源: Taylor
摘要:
The 12-coordinated hexakis(nitrato)europate(III) ion displays a luminescence spectrum compatible with Th, symmetry, with essentially a single emission line at 16 873 cm−1arising from the5D0→7F1transition. At low temperature (4.2 - 170 K), the lifetime of the5D0level amounts to 10.9 ms and then sharply decreases because of vibrational de-excitation processes (Ea= 2 250 ± 1 490 cm−1). The forbidden5D0→7F0transition displays an extensive pattern of Stokes and anti Stokes vibrational components and its energy reflects a nephelauxetic parameter for the nitrite ions δO(NO2) equal to -14.4, slightly larger than the one associated to the nitrate ion in [Eu(NO3)6]3-. The ligand excitation spectrum contains several bands displaying extensive vibrational structure mostly due to the δ(NO2) vibrational mode.
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