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Study of the Processing and Mechanical Properties ofIn SituComposite Materials of Thermoplastics with Thermotropic Liquid Crystalline Polymers

 

作者: Fang Shi,  

 

期刊: Polymer-Plastics Technology and Engineering  (Taylor Available online 1994)
卷期: Volume 33, issue 4  

页码: 445-455

 

ISSN:0360-2559

 

年代: 1994

 

DOI:10.1080/03602559408010739

 

出版商: Taylor & Francis Group

 

关键词: Liquid crystalline polymers;Mechanical properties;Polymer blends;Processing

 

数据来源: Taylor

 

摘要:

By blending thermoplastics (TPs)—polycarbonate (PC) and polyethersulfone (PES)—with thermotropic liquid crystalline polymers (TLCPs)—KU9221 and KU9231—and then extruding the blends to form fibers, thein situreinforcing characteristics were studied. The injection experiment of blends was compared with the extrusion experiment. According to the experimental results,in situreinforcing characteristics of these processes were analyzed theoretically. These researches have come to some important conclusions. TLCP domains can be transformed to form fibers that are oriented in the direction of flow during processing; these TLCP microfibers result in improved mechanical properties of the TP/TLCP blends. The extruding flow is more effective in orienting TLCP domains and results in betterin situreinforcement than that of injection molding, and the extruded fibers have better mechanical properties. The mechanical properties of the blend fibers are improved greatly with increasing tensile ratio of melt drawing and the content of TLCPs.

 

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