Study of the Processing and Mechanical Properties ofIn SituComposite Materials of Thermoplastics with Thermotropic Liquid Crystalline Polymers
作者:
Fang Shi,
期刊:
Polymer-Plastics Technology and Engineering
(Taylor Available online 1994)
卷期:
Volume 33,
issue 4
页码: 445-455
ISSN:0360-2559
年代: 1994
DOI:10.1080/03602559408010739
出版商: Taylor & Francis Group
关键词: Liquid crystalline polymers;Mechanical properties;Polymer blends;Processing
数据来源: Taylor
摘要:
By blending thermoplastics (TPs)—polycarbonate (PC) and polyethersulfone (PES)—with thermotropic liquid crystalline polymers (TLCPs)—KU9221 and KU9231—and then extruding the blends to form fibers, thein situreinforcing characteristics were studied. The injection experiment of blends was compared with the extrusion experiment. According to the experimental results,in situreinforcing characteristics of these processes were analyzed theoretically. These researches have come to some important conclusions. TLCP domains can be transformed to form fibers that are oriented in the direction of flow during processing; these TLCP microfibers result in improved mechanical properties of the TP/TLCP blends. The extruding flow is more effective in orienting TLCP domains and results in betterin situreinforcement than that of injection molding, and the extruded fibers have better mechanical properties. The mechanical properties of the blend fibers are improved greatly with increasing tensile ratio of melt drawing and the content of TLCPs.
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