Solute-Affected Vibrational Spectra of Water in Ca[C104)2Aqueous Solutions
作者:
Janusz Stangret,
期刊:
Spectroscopy Letters
(Taylor Available online 1988)
卷期:
Volume 21,
issue 5
页码: 369-381
ISSN:0038-7010
年代: 1988
DOI:10.1080/00387018808082314
出版商: Taylor & Francis Group
关键词: aqueous solutions;calcium perchlorate;vibrational spectra;ion-affected spectra;hydration phenomena
数据来源: Taylor
摘要:
A method of investigating hydration of a solute (beginning with infinite dilution) with the use of vibrational spectra has been presented. The procedure has been applied to aqueous Ca(C104)2solution spectra of OD(HDO) fundamental stretching vibration and combination vibrations of H2O (1100 – 1300 nm). The number of Ca(c104)2-affected water molecules has been determined; the obtained hydration spectra reveal anion-affected and cation-affected water bands.
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