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A new bath for the electrodeposition of aluminium. IV. The electrochemical behaviour of the rotating aluminium disc electrode in pure LiAlH4/THF‐toluene solutions

 

作者: W. A. Badawy,   N. Hilal,  

 

期刊: Berichte der Bunsengesellschaft für physikalische Chemie  （WILEY Available online 1989）
卷期: Volume 93, issue 1  

页码: 56-60

 

ISSN:0005-9021

 

年代: 1989

 

DOI:10.1002/bbpc.19890930111

 

出版商: Wiley‐VCH Verlag GmbH&Co. KGaA

 

关键词: Chemical Kinetics;Electrochemistry;Electrodeposition;Electrochemistry;Surfaces

 

数据来源: WILEY

 

摘要:

AbstractThe electrochemical behaviour of the rotating aluminium disc electrode in LiAlH4/tetrahydrofuran (THF)‐toluene solutions was studied. The kinetic parameters controlling the electrode process were investigated. The effect of concentration of LiAlH4, the speed of rotation of the rotating disc electrode, and the temperature on the current density‐potential behaviour of the aluminium electrode during the anodic and cathodic polarization was analyzed. The results were compared with those obtained for pur AlCl3or AlCl3+ LiAlH4/THF‐toluene solu

 

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