Thallium(I) Selective Solid Membrane Electrode
作者:
AjayK. Jain,
Sushma Agrawal,
RajP. Singh,
期刊:
Analytical Letters
(Taylor Available online 1979)
卷期:
Volume 12,
issue 9
页码: 995-1003
ISSN:0003-2719
年代: 1979
DOI:10.1080/00032717908059778
出版商: Taylor & Francis Group
关键词: thallium(I) molybdoarsenate;araldite;membrane;response;selectivity;end point indicator electrode
数据来源: Taylor
摘要:
Heterogeneous membranes of 2.0 cm diameter were prepared from a 60:40 mixture of thallium(I) molybdoarsenate and Araldite, These membranes gave near Nernstian response to thallium(I) ions over the concentration range 10−1to 10−3M but could be used for determination of thallium(I) down to 10−5M. Slope of the log concentration-potential plot is improved in 10 and 25 percent acetone-water mixture. The response was independent of pH over the range 4.0 to 6.0, The response time of the electrode is few seconds and potentials generated are reproducible. The selectivity of the electrode over a large number of cations was studied. The values of selectivity coefficients are of the order 10−2for monovalent and 10−3for bivalent cations. Anions did not interfere. Potentiometric-titration of thallium nitrate with potassium chromate was also done using the membrane as an end point indicator electrode.
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