Emission spectra between 288 and 458 nm from the photoionization of CO2by 58.4‐nm radiation have been obtained. The total cross sections for emission of theB2Σu+→X2ΠgandA2Πg→X2Πgsystems of CO2+are found to be 1.7 and 2.5×10−17cm2, respectively. Relative cross sections are given for the production of emission in individual vibrational features of theA→Xsystem. Previously unidentified bands in the CO2+A‐Xtransit