Further Determination of Cadmium Ions in Water by an Electrochemiluminescence Method
作者:
Paul J. Taverna,
Howard Mayfield,
Anthony R.J. Andrews,
期刊:
Analytical Letters
(Taylor Available online 1999)
卷期:
Volume 32,
issue 9
页码: 1821-1833
ISSN:0003-2719
年代: 1999
DOI:10.1080/00032719908542936
出版商: Taylor & Francis Group
关键词: chelation enhanced electrochemiluminescence;cadmium;terpyridine;bipyridine;aqueous solution
数据来源: Taylor
摘要:
Two new electrochemiluminescence (ECL) reactions in aqueous solution involving cadmium(II) ions are reported. The ECL reaction occurs in the presence of a common co-reactant, tripropylamine (TPA), and either of two organic ligands, 2,2′:6′,2″-terpyridine or 2,2′-bipyridine. The reaction is presumed to arise from the metal-ligand complex and the co-reactant. Conditions for ECL emission were optimised and a calibration graph constructed. Emission was linear over the range 10-1 000 ppb. The calculated limits of detection (LOD) were 8 and 50 ppb using terpyridine and bipyridine, respectively. Comparison with a previously reported reaction involving cadmium(II) ions and 1, 10-phenathroline is made.
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