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Lattice defects in (Hg,Cd)Te: Investigations of their nature and evolution

 

作者: H. F. Schaake,   J. H. Tregilgas,   A. J. Lewis,   P. M. Everett,  

 

期刊: Journal of Vacuum Science&Technology A: Vacuum, Surfaces, and Films  (AIP Available online 1983)
卷期: Volume 1, issue 3  

页码: 1625-1630

 

ISSN:0734-2101

 

年代: 1983

 

DOI:10.1116/1.572243

 

出版商: American Vacuum Society

 

关键词: semiconductor devices;quenching;recrystallization;vacancies;interstitials;tellurium;stoichiometry;self−diffusion;grain boundaries;dark conductivity;etching;annealing;mercury tellurides;cadmium tellurides

 

数据来源: AIP

 

摘要:

Brief summaries of the precipitation of tellurium in (Hg,Cd)Te during the quench from the recrystallization anneal of the solid state recrystallization process and the subsequent dissolution of these precipitates during the postanneal are given. It is shown that if vacancies and interstitials are considered to be the only important point defects in the lattice, the observed mechanisms of precipitation and annihilation require that tellurium in excess of stoichiometry must be accommodated by metal vacancies. Diffusion from the mercury ambient during postanneal then must occur by metal interstitials. Enhanced self‐diffusion on the metal sublattice is shown to occur along grain and subgrain boundaries. The most significant source of dark current in CID imagers fabricated on (Hg,Cd)Te is shown to be a sufficiently high dislocation density in a pixel.

 

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