Synthesis and Ionization of 1,1‐Dihalogenonaphtho[b]cyclopropenes
作者:
Paul Müller,
Huong Can Nguyen Thi,
期刊:
Israel Journal of Chemistry
(WILEY Available online 1981)
卷期:
Volume 21,
issue 2‐3
页码: 135-138
ISSN:0021-2148
年代: 1981
DOI:10.1002/ijch.198100029
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractThe synthesis of 1,1‐dichloro and 1,1‐difluoronaphtho[b]cyclopropenes 1 and 2 starting from 4,5‐dimethylenecyclohexene and tetrachloro‐ or 1,2‐dichloro‐3,3‐ difluorocyclopropene, respectively, is described. Both 1 and 2 ionize in cold fluorosulfonic acid to yield stable aromatic cations 3 and 4. Upon quenching with water, 1‐chloronaphtho[b]cyclopropenium ion 3 affords
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