The behaviour of poly(2,3‐epoxypropyl methacrylate) in dilute solution
作者:
Libuše Mrkvičková,
Jaroslav Kálal,
Bohumil Bednář,
Josef Janča,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1982)
卷期:
Volume 183,
issue 1
页码: 203-210
ISSN:0025-116X
年代: 1982
DOI:10.1002/macp.1982.021830118
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractHomopolymers of 2,3‐epoxypropyl methacrylate with various molecular masses were prepared by solution polymerization with 2,2′‐azoisobutyronitrile as initiator. The effect of polymerization conditions on the molecular parameters (weight‐ and number‐average molecular massesMWandMnintrinsic viscosity [η]) and the tacticity of the resulting poly (2,3‐epoxypropyl methacrylate)s was investigated. For unfractionated polymers, the constants of the Mark‐Houwink equation for 1,4‐dioxane and tetrahydrofuran were determined. Gel permeation chromatography was tested as a tool for the determination of
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