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Patterns of fragmentation for polymer coatings

 

作者: UlrichA. Handge,   IgorM. Sokolov,   Alexander Blumen,   Evelyne Kolb,   Eric Clément,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1999)
卷期: Volume 38, issue 5-6  

页码: 971-980

 

ISSN:0022-2348

 

年代: 1999

 

DOI:10.1080/00222349908248152

 

出版商: Taylor & Francis Group

 

关键词: Disordered systems;Fracture mechanics;Fragmentation;Nonlinear elasticity;Pattern formation;Random processes.

 

数据来源: Taylor

 

摘要:

We investigated the fragmentation of thin coatings on substrates under uniaxial tension. Theoretical models based on linear elasticity predict a power-law dependence of the mean fragment length <L> on the strain e to which the substrate is subjected: namely, one has <L> ∞ε−αwith α ≤ 1/2. Experimentally, such a relation is obeyed in the fragmentation of thin SiOxcoatings on polyethylene terephthalate (PET) substrates. In our experiments, we used brittle paints to coat rubber substrates: the ensuing mean fragment lengths also obey power laws in ε: we found, however, α = 0.71 ± 0.03. Such values of α can be reproduced theoretically by taking into account the nonlinearity of the coupling between coating and substrate.

 

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