Influence of Chemical Pressure and Reaction-Induced Stress in Solid-State Reaction: Lattice Instability during the Thermally Enhanced Reaction of MSE
作者:
J. Even,
M. Bertault,
J. Gallier,
A. Girard,
Y. Delugeard,
C. Ecolivet,
S. Beaufils,
L. Toupet,
W.J. Kusto,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 313,
issue 1
页码: 135-144
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808044267
出版商: Taylor & Francis Group
关键词: organic crystals;elasticity;phase transitions;solid-state reaction
数据来源: Taylor
摘要:
A p-dimethylaminobenzenesulfonate (MSE) polycrystalline powder is converted to the zwitterion p-trimethylammoniumbenzenesulfonate (ZWT) by chemical thermally induced reaction at T = 55,5°C. This reaction is associated to a first order ferroelastic phase transition in partially reacted MSE crystals. A13C-NMR study made during the in situ transformation MSE → ZWT shows that the reaction is of first order. A strong change appears in the low frequency Raman and Brillouin spectra of MSE monocrystals when passing the transition, but only a continuous evolution in the intensity of the high frequency modes is observed. Birefringence observations permit to specify the evolution of the optical axes position during the chemical reaction. The importance of stress induced by the reaction is discussed in relation to the phase transition.
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