The thermal desorption of surface species from sulfur dioxide adsorption on natural chrysotile asbestos and calorimetric sorption heats at 298, 323, 373, and 423 K
作者:
William John Murphy,
Robert Anderson Ross,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1978)
卷期:
Volume 56,
issue 14
页码: 1847-1852
ISSN:0008-4042
年代: 1978
DOI:10.1139/v78-300
出版商: NRC Research Press
数据来源: NRC
摘要:
Calorimetric heats of adsorption have been determined for sulfur dioxide adsorbed at 298, 323, 373, and 423 K on both Californian and Quebec chrysotiles. Adsorption isotherms have been measured and some differential molar entropies calculated. Thermal desorption of surface species resulting from the adsorption of sulfur dioxide on Californian chrysotile at 298 K have been studied from 25 to 450 °C. Sulfurous and carbonic acids, in addition to sulfites and other trace species, have been shown to result from the adsorbent–adsorbate interactions. A mechanism for sulfur dioxide adsorption on chrysotile has been prepared which accounts for the observed high heats of adsorption measured at low surface coverages.
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