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Crystal and Molecular Structures of Two AZA-Heterocyclic Derivatives of 6-Thio-D-Galactopyranose

 

作者: Anne Imberty,   Nadine Mouhous-Riou,   Patrick Rollin,   Stéphanie Cassel,   Christelle Lorin,   Serge Pérez,  

 

期刊: Journal of Carbohydrate Chemistry  (Taylor Available online 1998)
卷期: Volume 17, issue 6  

页码: 923-936

 

ISSN:0732-8303

 

年代: 1998

 

DOI:10.1080/07328309808007464

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The conformations of crystalline 6-C-(benzothiazol-2-yl)sulfonyl-6-deoxy-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose (1) andSR-6-deoxy-1,2:3,4-di-O-isopropylidene-6-C-(2-pyridyl)sulfinyl-α-D-galactopyranose (2) have been determined by X-ray diffraction. The crystal structure of1belongs to the monoclinic P21space group witha= 10.779(4),b= 10.431(6),c= 10.258(6) Å) and β =113.51(2)°C. The crystal structure of2belongs to the tetragonal space P41212 witha= 10.652(2) andc= 33.037(4) Å. The molecular features of these two compounds are compared with those of the related 6-S-(benzoxazol-2-yl)-1,2:3,4-di-O-isopropylidene-6-thio-α-D-galactopyranose (3).

 

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