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Hard and Soft-Core Equations of State for Simple Fluids : III Characteristic Curves and Hard-core Equations of State

 

作者: John Stephenson,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1979)
卷期: Volume 8, issue 4  

页码: 265-270

 

ISSN:0031-9104

 

年代: 1979

 

DOI:10.1080/00319107908084757

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Explicit formulae are presented for those characteristic curves which can be constructed for a hard-core equation of state. Excellent agreement is obtained with experimental curves for argon up to fairly high pressures (20Pc) and temperatures (10Tc). It is shown that only three termination temperatures are obtainable from a hard-core type second virial coefficient. The limitations of the hard-core equation of state are discussed briefly.

 

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