Pseudopotential Method for the Thermodynamic Properties of Liquid Alkali Metals
作者:
R.N. Singh,
V.N. Singh,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1991)
卷期:
Volume 22,
issue 4
页码: 235-243
ISSN:0031-9104
年代: 1991
DOI:10.1080/00319109108030625
出版商: Taylor & Francis Group
关键词: Enthalpy;compressibility;stability
数据来源: Taylor
摘要:
A pseudopotential method has been considered to study the enthalpy and compressibility of liquid alkali metals (Na, K, Rb and Cs) as a function of temperature. The diameters of the hard sphere reference system were determined by minimising the Helmholtz free energy to ensure thermodynamic stability. The enthalpy, which depends weakly on temperature, has been successfully explained. The investigation suggests that the structure dependent part of energy is sufficient to explain the compressibility of liquid alkali metals near and above the melting temperatures.
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