Thermochemical Investigations of Tautomeric Equilibrium. Variation of the Calculated Equilibrium Constant with Binary Solvent Composition
作者:
WilliamE. Acree,
SherylA. Tucker,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1989)
卷期:
Volume 20,
issue 2-3
页码: 135-145
ISSN:0031-9104
年代: 1989
DOI:10.1080/00319108908036400
出版商: Taylor & Francis Group
关键词: Tautomeric equilibria;thermodynamic model;binary solvent;solute-solvent complexation;molecular complexation;equilibrium constants
数据来源: Taylor
摘要:
A conventional nonelectrolyte solution model which has led to successful predictive equations for solute solubility and infinite dilution chromatographic partition coefficients is extended to systems containing a tautomeric solute dissolved in a binary solvent mixture. The derived expression predicts that the tautomeric solute concentration in a binary solvent is a geometric average of the pure solvent ratios and permits calculation of solute-solvent association constants from variation of the stoichiometric tautomeric solute concentration ratios as a function of binary solvent composition. Experimental data for phenylazonaphthol dissolved in aqueous-ethanol and aqueous-acetone solvent mixtures is discussed in relation to the theoretical model.
点击下载:
PDF (481KB)
返 回