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Cyclic Voltammetry and Electron Paramagnetic Resonance Studies of Some Analogues of Nifurtimox.

 

作者: C. Qlea-Azar,   Ana Maria Atria,   Fernando Mendizabal,   Rossana di Maio,   G. Seoane,   Hugo Cerecetto,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1998）
卷期: Volume 31, issue 1  

页码: 99-109

 

ISSN:0038-7010

 

年代: 1998

 

DOI:10.1080/00387019808006764

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The EPR of radicals obtained by electrolytic reduction of some new analogues of the antiprotozoal drug nifurtimox were measured in DMSO and DMF. The electrochemistry of these compounds was studied using cyclic voltammetry AM1 and INDO semiempirical molecular orbital calculations were performed to obtain the optimized geometries and spin distribution, respectively. Density functional theory was used to rationalize the reduction potentials of these compounds.

 

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