Experimental studies of line shapes from a Balle–Flygare spectrometer
作者:
Edward J. Campbell,
Frank J. Lovas,
期刊:
Review of Scientific Instruments
(AIP Available online 1993)
卷期:
Volume 64,
issue 8
页码: 2173-2178
ISSN:0034-6748
年代: 1993
DOI:10.1063/1.1143956
出版商: AIP
数据来源: AIP
摘要:
The line shape problem for the Balle–Flygare‐type microwave spectrometer is reexamined experimentally using the method of sine and cosine Fourier transforms with a phase correction. Two previous studies [E. J. Campbell, L. W. Buxton, T. J. Balle, M. R. Keenan, and W. H. Flygare, J. Chem. Phys.74, 829 (1981), and F. J. Lovas and R. D. Suenram, J. Chem. Phys.87, 2010 (1987)] are reviewed. Those results are combined with new experimental data to obtain a general description of line shapes obtained from this device. Our emphasis here will be on using specific examples to clarify the relationship between the frequency domain representations of experimentally measured time‐domain signals and the originating active species distributions.
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