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Experimental studies of line shapes from a Balle–Flygare spectrometer

 

作者: Edward J. Campbell,   Frank J. Lovas,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1993)
卷期: Volume 64, issue 8  

页码: 2173-2178

 

ISSN:0034-6748

 

年代: 1993

 

DOI:10.1063/1.1143956

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The line shape problem for the Balle–Flygare‐type microwave spectrometer is reexamined experimentally using the method of sine and cosine Fourier transforms with a phase correction. Two previous studies [E. J. Campbell, L. W. Buxton, T. J. Balle, M. R. Keenan, and W. H. Flygare, J. Chem. Phys.74, 829 (1981), and F. J. Lovas and R. D. Suenram, J. Chem. Phys.87, 2010 (1987)] are reviewed. Those results are combined with new experimental data to obtain a general description of line shapes obtained from this device. Our emphasis here will be on using specific examples to clarify the relationship between the frequency domain representations of experimentally measured time‐domain signals and the originating active species distributions.

 

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