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Electrochemistry of 4-Picoline Complexes of Hemin

 

作者: D.G. Davis,   L.M. Bynum,  

 

期刊: Analytical Letters  （Taylor Available online 1975）
卷期: Volume 8, issue 3  

页码: 139-145

 

ISSN:0003-2719

 

年代: 1975

 

DOI:10.1080/00032717508058193

 

出版商: Taylor & Francis Group

 

关键词: Polarography;cyclic voltammetry;4-picoline;hemin;iron porphyrin

 

数据来源: Taylor

 

摘要:

Cyclic voltammetry and polarography were used to investigate the complexes formed between hemin and 4-picoline in aqueous ethanol solutions. The number of ligands and the effect of pH on the polarographic wave were determined and used to elucidate the mechanism of the electrode reactions. Cyclic voltammetry confirmed the proposed mechanisms. Equilibrium constants were determined where possible.

 

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