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Absorption Spectra of Benzene Cation Radical, Chlorobenzene Cation Radical, and Fluorobenzene Cation Radical in Perfluorocarbon Polymer Film at 77K

 

作者: Y. Kodera,   T. Hikida,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1989）
卷期: Volume 22, issue 9  

页码: 1229-1239

 

ISSN:0038-7010

 

年代: 1989

 

DOI:10.1080/00387018908054019

 

出版商: Taylor & Francis Group

 

关键词: Absorption Spectra;Cation Radical;Matrix.

 

数据来源: Taylor

 

摘要:

Absorption spectra of benzene cation radical, chlorobenzene cation radical, and fluorobenzene cation radical have been obtained in perfluorocarbon polymer at 77 K. Cation radicals are formed in good yields and less perturbed electronic absorption spectra are obtained. Results demonstrate that perfluorocarbon polymer is suitable as matrix for spectroscopic investigation of the cation radicals formed by γ-irradiation.

 

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