The Preparation of Ipns of Polystyrene-Polyethylene and Poly(Butyl Methacrylate)-Polyethylene and Their Dynamic Mechanical Behavior
作者:
E. Borsig,
J. Hrouz,
A. Fiedlerová,
M. Ilavský,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1990)
卷期:
Volume 27,
issue 13-14
页码: 1613-1620
ISSN:0022-233X
年代: 1990
DOI:10.1080/00222339009351505
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
IPNs based on polyethylene and vinyl polymers were prepared according to a new procedure. We studied the dynamic mechanical behavior of two series of IPNs: polystyrene (PS)-polyethylene (PE) and poly(butyl methacrylate) (PBMA)-PE at the frequency ω = 1 Hz and in the temperature region from −50 to 200°C. Temperature dependences of the components of the dynamic modulus of elasticity G' and G" of the networks PS and PBMA have shapes typical of amorphous networks; the corresponding dependences of pure PE show, however, features typical of a semicrystalline polymer. IPNs of the system PS/PE show two-phase behavior. AtT< 110°C, PE functions as a plasticizer. In the system PBMA/PE, better miscibility of components is seen, and PE exerts a reinforcing effect on the mechanical behavior over the whole temperature region. In both systems, network density increases with increasing PE content in IPNs. Better homogeneity and a slight increase in the network density of IPNs with PBMA/PE in comparison to PS/PE networks are probably caused by a greater number of grafted PBMA chains in the PE network compared to the PS network.
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