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Synthesis of Sialyl Lewis X Analogues

 

作者: Gyula Dekany,   Karen Wright,   Peter Ward,   Istvan Toth,  

 

期刊: Journal of Carbohydrate Chemistry  （Taylor Available online 1996）
卷期: Volume 15, issue 4  

页码: 383-398

 

ISSN:0732-8303

 

年代: 1996

 

DOI:10.1080/07328309608005661

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Sialyl Lewis X (SLex) analogs2aand2bwere synthesised, where theN-acetyl-D-glucose and the D-galactose units of SLex1were replaced with an alkyl and a heteroalkyl spacer. Sulphate ester6iwas also synthesised from alcohol6band chlorosulphonic acid. A novel promoter, silver mercaptoethanesulphonate, was used to synthesise α-sialosides2c. 7band7c.

 

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