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Novel Copper-Tartrate Coordination Compounds

 

作者: NeilD. Jespersen,  

 

期刊: Analytical Letters  （Taylor Available online 1972）
卷期: Volume 5, issue 7  

页码: 497-508

 

ISSN:0003-2719

 

年代: 1972

 

DOI:10.1080/00032717208064332

 

出版商: Taylor & Francis Group

 

关键词: Thermometric enthalpy titration;TET;copper (II);tartrate;bitartrate;hexa-ligand;kinetics

 

数据来源: Taylor

 

摘要:

Using the thermometric enthalpy titration methodology, the hexa-ligand species CuT6[where T represents the tartrate ion and charges are omitted] has been shown to exist even in dilute tartrate solutions. Kinetic considerations suggest a radical difference between CuT3CuT2and the more highly coordinated species CuT3, CuT4, CuT5and CuT6. It is evident that the hydroxyl groups on the tartrate ion are singularly important contributers to this effect

 

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