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Observation of textures of nematic polymers and estimation of the elastic constants

 

作者: T. De'Nève,   M. Kléman,   P. Navar,  

 

期刊: Liquid Crystals  (Taylor Available online 1995)
卷期: Volume 18, issue 1  

页码: 67-71

 

ISSN:0267-8292

 

年代: 1995

 

DOI:10.1080/02678299508036592

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The texture of a copolyesteramide, Vectra® B950, has been studied by optical microscopy. At rest, the defects are typical of a biaxial nematic phase, but under the influence of a magnetic field or under shear, the nematic transforms into a uniaxial phase. The Freedericksz geometry yields aK1elastic constant of the order of 10−8N. The diffusivitiesKIII/nandKII/nare obtained by measuring the light intensity transmitted through a sample during shear start-up and relaxation, and from this we estimateKIII≅ 10−9N andKII≅ 10−10N. Since the biaxiality is small, these uniaxial constants adequately describe the phase at rest.

 

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