Observation of textures of nematic polymers and estimation of the elastic constants
作者:
T. De'Nève,
M. Kléman,
P. Navar,
期刊:
Liquid Crystals
(Taylor Available online 1995)
卷期:
Volume 18,
issue 1
页码: 67-71
ISSN:0267-8292
年代: 1995
DOI:10.1080/02678299508036592
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The texture of a copolyesteramide, Vectra® B950, has been studied by optical microscopy. At rest, the defects are typical of a biaxial nematic phase, but under the influence of a magnetic field or under shear, the nematic transforms into a uniaxial phase. The Freedericksz geometry yields aK1elastic constant of the order of 10−8N. The diffusivitiesKIII/nandKII/nare obtained by measuring the light intensity transmitted through a sample during shear start-up and relaxation, and from this we estimateKIII≅ 10−9N andKII≅ 10−10N. Since the biaxiality is small, these uniaxial constants adequately describe the phase at rest.
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