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Effect of Visible Light on the Dimerization of Cobalt (II) Tetrasulfonated Phthalocyanine in Water

 

作者: ReginaldP. Seiders,   J.Richard Ward,  

 

期刊: Analytical Letters  （Taylor Available online 1984）
卷期: Volume 17, issue 15  

页码: 1763-1769

 

ISSN:0003-2719

 

年代: 1984

 

DOI:10.1080/00032718408065349

 

出版商: Taylor & Francis Group

 

关键词: Cobalt (II) tetrasulfonated phthalocyanine;dyestuff photochemistry;UV-VIS spectrometry;dimerization constants

 

数据来源: Taylor

 

摘要:

Beelen and coworkers in the Netherlands recently reported that visible light enhanced the rate of selective oxidation of mercaptoethanol by dioxygen, catalyzed by cobalt (II) tetrasulfonated phthalocyanine (CoTSPC). The Dutch workers speculated that visible light promoted disaggregation of CoTSPC, producing more of the catalytically active monomer.

 

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