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Determination of static dielectric constant-temperature-density surfaces of a Stockmayer fluid by perturbation theory

 

作者: Saul Goldman,  

 

期刊: Molecular Physics  (Taylor Available online 1990)
卷期: Volume 71, issue 3  

页码: 491-507

 

ISSN:0026-8976

 

年代: 1990

 

DOI:10.1080/00268979000101931

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Second-order perturbation theory is applied to a Stockmayer fluid to obtain its static dielectric constant over a range of temperatures, densities and dipole moments. A discrepancy in the literature, associated with this calculation, is identified and explained. An explanation is also provided for the fact that the theory predicts the dielectric constant accurately for low to moderately high dipole moments, while it is very inaccurate in its prediction of angular structure.

 

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