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Interfacial properties and phase transitions of a system of anisotropic molecules

 

作者: Peter Harrowell,   DavidW. Oxtoby,  

 

期刊: Molecular Physics  (Taylor Available online 1985)
卷期: Volume 54, issue 6  

页码: 1325-1333

 

ISSN:0026-8976

 

年代: 1985

 

DOI:10.1080/00268978500101031

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

By employing an anisotropic scaling of the cartesian coordinates, the properties of a system of perfectly aligned ellipsoidal molecules can be exactly related to the analogous properties of a system of spherical molecules. This approach is used to determine for such a model system the structure of the liquid surface and the orientational dependence of the surface tension. It is found that the surface tension and surface stiffness are no longer equal as they are in an isotropic liquid. The smectic phase is absent, while a continuum of crystal phases exist, differing in the relative orientation between the molecular axis and the crystal axis.

 

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