Interfacial properties and phase transitions of a system of anisotropic molecules
作者:
Peter Harrowell,
DavidW. Oxtoby,
期刊:
Molecular Physics
(Taylor Available online 1985)
卷期:
Volume 54,
issue 6
页码: 1325-1333
ISSN:0026-8976
年代: 1985
DOI:10.1080/00268978500101031
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
By employing an anisotropic scaling of the cartesian coordinates, the properties of a system of perfectly aligned ellipsoidal molecules can be exactly related to the analogous properties of a system of spherical molecules. This approach is used to determine for such a model system the structure of the liquid surface and the orientational dependence of the surface tension. It is found that the surface tension and surface stiffness are no longer equal as they are in an isotropic liquid. The smectic phase is absent, while a continuum of crystal phases exist, differing in the relative orientation between the molecular axis and the crystal axis.
点击下载:
PDF (456KB)
返 回