Simplified RPA Bhatia—Young Calculations of the Phase Diagram for a Model Binary Mixture. I. Equal Size Molecules
作者:
S.M. Osman,
M. Silbert,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1991)
卷期:
Volume 23,
issue 4
页码: 239-250
ISSN:0031-9104
年代: 1991
DOI:10.1080/00319109108027260
出版商: Taylor & Francis Group
关键词: Mixtures;random phase approximation
数据来源: Taylor
摘要:
We present the results of calculations of the phase diagram for a model binary mixture of equal size hard-core molecules interacting via square-well potentials, but assuming that the system does not satisfy Berthelot rule. In particular, we analyse the effects that the parameter which measures departures from this rule has on the phase diagram of the system. The calculations are based on the Bhatia—Young model for the bulk properties of liquid mixtures.
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