A study of case II diffusion of a fluorinated hydrocarbon in poly(styrene) by resonance nuclear reaction analysis
作者:
Kenji Umezawa,
Walter M. Gibson,
John T. Welch,
Koichi Araki,
Glaucione Barros,
Harry L. Frisch,
期刊:
Journal of Applied Physics
(AIP Available online 1992)
卷期:
Volume 71,
issue 2
页码: 681-684
ISSN:0021-8979
年代: 1992
DOI:10.1063/1.351327
出版商: AIP
数据来源: AIP
摘要:
The diffusion of a fluorinated hydrocarbon into glassy poly(styrene) (PS) was studied by using resonance nuclear reaction analysis. It was found that; (1) the activation energy derived from measured diffusion coefficients is in good agreement with the value calculated from measured induction times, (2) the diffusion coefficient depends on molecular weight of PS, reflecting the dependence of the mobility on the polymer chain matrix, (3) the mathematical foundation of Lasky and Kramer provides a framework to obtain swelling kinetics from the experimental diffusion measurements.
点击下载:
PDF
(453KB)
返 回