Termination Rates in Free Radical Copolymerizations
作者:
S.S. M. Chiang,
Alfred Rudin,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1975)
卷期:
Volume 9,
issue 2
页码: 237-256
ISSN:0022-233X
年代: 1975
DOI:10.1080/00222337508068659
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The rates of free radical copolymerizations at given rates of initiation can be analyzed ideally in terms of monomer feed concentrations and reactivity ratios, propagation rate constants for homopolymerizations of the particular monomers, and an overall rate constant for termination during copolymerization. This model, which is due to Atherton and North, can account for the effects of initiator concentration and viscosity of the polymerization medium on copolymerization rates.
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