Halochrome Molekeln. 7. Mitteilung. Synthese und acidobasisches Verhalten substituierter Heteroarenochinazoline
作者:
Sigmund Gunzenhauser,
Heinz Balli,
期刊:
Helvetica Chimica Acta
(WILEY Available online 1988)
卷期:
Volume 71,
issue 1
页码: 33-46
ISSN:0018-019X
年代: 1988
DOI:10.1002/hlca.19880710105
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
Halochromic Molecules. Synthesis and Acidobasic Properties of Substituted HeteroarenoquinazolinesWe have synthetized a series of substituted heteroarenoquinazolines. The 90‐MHz FT1H‐NMR spectra of starting and final products supported the postulated structures. Fragmentation in the mass spectra also were consistant with the assumed structures. With acid, the compounds partly from ring‐opened, intensely coloured triphenylcarbenium salts of the Rhoduline‐R type (C. I. 42565). UV/VIS spectra of the salts are discussed on the basis of VEPPP‐CI calculations. The ϵpH*curves in buffered MeOH/H2O solutions and the pK* values are determined. The title compounds undergo very complex protonation
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