POLAROGRAPHIC DETERMINATION OF BENZOYL PEROXIDE AND CUMENE HYDROPEROXIDE
作者:
Paul A. Giguère,
D. Lamontagne,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1951)
卷期:
Volume 29,
issue 1
页码: 54-59
ISSN:0008-4042
年代: 1951
DOI:10.1139/v51-007
出版商: NRC Research Press
数据来源: NRC
摘要:
Benzoyl peroxide and cumene hydroperoxide (CHP) are reduced at the anodically polarized dropping mercury electrode, the former at about +0.3 volt vs. S.C.E., and the latter at +0.1 v. Their half-wave potentials as well as that of the two reduction steps of dissolved oxygen are gradually shifted towards more negative values with increasing concentration of organic peroxides. The polarographic method is suitable for determining these peroxides in concentrations up to 2 × 10−3 mole per liter. Dissolved oxygen does not interfere seriously with the analyses.
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