Analysis of the A3(X3)3nuclear spin system and π-electron coupled hyperfine splitting constants in aromatic hydrocarbons
作者:
J.V. Acrivos,
期刊:
Molecular Physics
(Taylor Available online 1962)
卷期:
Volume 5,
issue 1
页码: 1-14
ISSN:0026-8976
年代: 1962
DOI:10.1080/00268976200100011
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The nuclear spin functions for the A3(X3)3system have been developed and used to analyse the NMR spectra of (CH3)3C6H3and (CF3)3C6H3. The π-electron coupled hyperfine splitting constants, obtained from the Ramsey theory with simple Hückel M.O.'s for benzene and without the assumption of an average energy of excitation for the virtual processes which give rise to the coupling, are in agreement with the hyperfine constants observed between the methyl groups and the ring protons in the above compounds.
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