The Free-Radical Chemistry of Fluoroketones. II. Reaction with Unsaturated Compounds
作者:
E.G. Howard,
P.B. Sargeant,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1967)
卷期:
Volume 1,
issue 6
页码: 1011-1023
ISSN:0022-233X
年代: 1967
DOI:10.1080/10601326708053754
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Free radicals induce two principal types of interaction between fluoro-ketones and olefins, both of which lead to polymeric products. Copolym-erization of the fluoroketone through its carbonyl group leads to poly-ethers. Hydrogen abstraction, presumed to be largely intramolecular, also occurs to give highly branched polymers with fluoroalcohol groups at terminal positions on the branches.
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