Origins of the Pfeiffer effect
作者:
R.D. Gillard,
P.A. Williams,
期刊:
International Reviews in Physical Chemistry
(Taylor Available online 1986)
卷期:
Volume 5,
issue 2-3
页码: 301-305
ISSN:0144-235X
年代: 1986
DOI:10.1080/01442358609353395
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The Pfeiffer effect concerns the change in optical activity of a solution containing a chiral substance, the environment compound, when a racemic mixture of another substance, classically a coordination complex of diimine ligands, is added to it. Several mechanisms have been proposed to account for the effect and these are discussed with respect to specific interactions leading to the observed chiral discriminations. Some new related systems involving Ru(II) complexes are reported.
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